Химия 9кл_Габриелян_ГДЗ_2002
.pdf7. Be(OH) + H SO = BeSO ↓ G H
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Z%H 2+ G <_ G H%H 2+ G H
2 + 2+ 2 G H 2 + H2SO4=BeSO4 2
[Be(OH)%H 2++ 2HNO2G3=Be(NO<_2 3)2 G H2%H 2+
G2H 2 – 2– 2G H 2 + 2KOH=K2BeO2 + Be(OH) + 2NaOH=Na BeO
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Gh kms_kl\mxl2SO4; dbkehluP2O5; COh[jZah\Zggu2. _ f_lZeeZfb
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Hkgh\gu_ k\hckl\Z oZjZdl_jgu ijZdlbq_kdb lhevdh ^ey f_lZeeh\
GZijbf_j NaOH, K2O, LiNO3.
I_jbh^bq_kdbc aZdhg b i_jbh^bq_kdZy kbkl_fZ § 3 obfbq_kdbo we_f_glh\ > B F_g^_e__\Z
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Jmdh\h^kl\mykv i_jbh^bq_kdhc kbkl_fhc gZc^_f we_f_gl k gm`guf jZkiheh`_gb_f we_dljhgh\ b Wlhl we_f_gl ²Zahl
NWlhl: 1swe22s_2f2p_gl3. h[jZam_l ijhklh_ \_s_kl\h Zahl <h^hjh^gh_
kh_^bg_gb_ ZahlZ — NH3 ZffbZd <ukrbc—hdkb^N2, ZahlZ — N2H5.
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Dbkehlguc hdkb^ ijb jZkl\hj_gbb \ \h^_ i_j_oh^bl \ kbevgmx Zahlgmx dbkehlmN2O5 +123.
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N2O5 + H2O = 2HNO3; |
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N2O5 + BaO = Ba(NO3)2; |
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N5+ h[eZ^Z_l kbevgufb hdbkebl evgufb k\hckl\Zfb |
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N2O5 |
+ Ba(OH)2 = Ba(NO3)2 + H2O; |
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2N2O5 K = 2N2 K22. |
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qbk_e |
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We_f_gl ‹ 7 — N, |
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we_f_gl ‹ 8 — O. |
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MjZ\g_gby j_Zdpbc |
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KZ + N2 |
KZ3N , |
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KZ + O2 |
KZ2 |
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Ijh^mdlu j_Zdpbc bf_xl bhgguc lbi k\yab |
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:ahl b dbkehjh^ bf_xl fhe_dmeyjgh_ kljh_gb_ djbklZeebq_kdbo |
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j_r_lhd Z m dZevpby f_lZeebq_kdZy djbklZeebq_kdZy j_r_ldZ |
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Ijh^mdlu \aZbfh^_ckl\by ²KZ3N2 |
b KZ2bf_xl bhggh_ kljh_gb_ |
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djbklZeebq_kdhc j_r_ldb |
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<hijhk mkbe_gb_ f_lZeebq_kdbo k\hckl\
N, P,F_As,lZeebqS , _Bikdb—_ k\hckl\Z \ ]jmiiZo mkbeb\Zxlky
<hijhk mkbe_gb_ g_f_lZeebq_kdbo k\hckl\ GNa,_fMg,_lZeebqAl, Si,_kdbP,_S,k\hckl\ZCl — \ i_jbh^Zo mkbeb\Zxlky
<hijhk mf_gvr_gb_ dbkehlguo k\hckl\Cl2O7, P2O5, SiO2, Al2O3, MgO, Na2O —
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Dbkehlgu_ k\hckl\Z \ i_jbh^Zo m\_ebqb\Zxlky |
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+KO24, H3PO4, H2SiO4, Al(OH)3, Mg(OH)2, NaOH — mf_gvr_gb_ |
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dbkehlguo k\hckl\ |
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<hijhk |
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B2O3, BeO, Li2O²\hajZklZgb_ hkgh\guo k\hckl\ l d \ i_jbh^Zo |
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hkgh\gu_ k\hckl\Z hkeZ[_\Zxl |
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B(OH)3, Be(OH)2, LiOH — \hajZklZgb_ hkgh\guo k\hckl\ |
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B(OH)3 — keZ[Zy dbkehlZ |
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Be(OH)2 — keZ[h_ hkgh\Zgb_ |
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LiOH — kbevgh_ hkgh\Zgb_ |
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I_jbh^bq_kdZy kbkl_fZ |
we_f_glh\ |
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obfbq_kdbo we_f_glh\ :lhfguc ghf_j we_f_glZ jZ\_g aZjy^m y^jZ |
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qbke_ggh hg jZ\_g qbkem ijhlhgh\ Qbkeh g_cljhgh\ kh^_j`Zsboky \ |
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y^jZo h^gh]h we_f_glZ \ hlebqb_ hl qbkeZ ijhlhgh\ fh`_l [ulv |
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jZaebqguf :lhfu h^gh]h we_f_glZ y^jZ dhlhjuo kh^_j`Zl jZagh_ |
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qbkeh g_cljhgh\ gZau\Zxlky bahlhiZfb |
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DZ`^uc obfbq_kdbc we_f_gl bf__l |
ih g_kdhevdh bahlhih\ |
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ijbjh^guo beb ihemq_gguo bkdmkkl\_ggh :lhfgZy |
fZkkZ |
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obfbq_kdh]h we_f_glZ jZ\gZ kj_^g_fm agZq_gbx ba fZkk \k_o _]h |
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ijbjh^guo bahlhih\ k mq_lhf bo jZkijhkljZg_gghklb |
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K hldjulb_f bahlhih\ ^ey jZkij_^_e_gby we_f_glh\ ih |
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i_jbh^bq_kdhc kbkl_f_ klZeb bkihevah\Zlv aZjy^u y^_j Z g_ bo |
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Zlhfgu_ fZkku |
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aZ\bkyl g_ hl h[s_]h qbkeZ we_dljhgh\ Z lhevdh hl \Ze_glguo |
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dhlhju_ gZoh^ylky gZ ihke_^g_f keh_ Dhebq_kl\h \Ze_glguo |
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we_dljhgh\ f_gy_lky i_jbh^bq_kdb ke_^h\Zl_evgh k\hckl\Z |
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we_f_glh\ lZd`_ f_gyxlky i_jbh^bq_kdb |
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K\hckl\Z obfbq_kdbo we_f_glh\ b h[jZah\Zgguo bfb \_s_kl\ |
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gZoh^ylky \ i_jbh^bq_kdhc aZ\bkbfhklb hl hlghkbl_evguo Zlhfguo |
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fZkk we_f_glh\ |
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K\hckl\Z |
obfbq_kdbo |
we_f_glh\ b h[jZah\Zgguo bfb \_s_kl\ |
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gZoh^ylky \ i_jbh^bq_kdhc |
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aZ\bkbfhklb |
hl aZjy^Z Zlhfguo |
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=eZ\Z F_lZeeu
<hijhk § 4 <_d f_^guc [jhgah\uc `_e_aguc
< wihom Zglbqghklb k_fvx qm^_kZfb k\_lZ kqblZeb _]bi_lkdb_ ibjZfb^u \bkyqb_ kZ^u <Z\behgZ klZlmx DhehkkZ Jh^hkkdh]h OjZf :jl_fb^u \ Wn_k_ klZlmx hebfibckdh]h [h]Z Xibl_jZ fZ\ahe_c \ =ZebdZjbZk_ :e_dkZg^jbckdbc fZyd
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fZl_jbZeu we_dljhl_ogbq_kdb_ fZl_jbZeu `Zjhijhqgu_ fZl_jbZeu
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Iheh`_gb_ f_lZeeh\ \ i_jbh^bq_kdhc kbkl_f_ § 5 > B F_g^_e__\Z b kljh_gb_ bo Zlhfh\
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§ 7 KieZ\u |
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;jhgah\uc \_d ijh^he`Zeky ijb[ebabl_evgh e_l dhg_p — |
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gZqZeh lukyq_e_lby ^h g w GZa\Zgb_©[jhgah\uc \_dªh[mkeh\e_gh |
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l_f qlh \ wlhl i_jbh^ rbjhdh bkihevah\Zeky kieZ\ f_^b b heh\Z |
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dhlhjuc ihemqbe gZa\Zgb_ [jhgaZ |
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<hijhk |
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F_evobhj ² kieZ\ kh^_j`Zsbc hdheh f_^b b gbd_ey |
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Ihwlhfm ^ey ijhba\h^kl\Z d] f_evobhjZ g_h[oh^bfh \aylv |
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P &X |
Pf_evobhjZ ω KX\ kieZ\_ = 25 |
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P 1L |
Pf_evobhjZ ω(Ni)\ kieZ\_ = 25 |
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Hl\_l d]&Xb d]1L |
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Hq_\b^gh qlh hgb ijhbkoh^yl hl h^gh]h b lh]h `_ keh\Z E_]bjmxsb_ we_f_glu ^h[Z\eyxl \ kieZ\ qlh[u memqrblv bo nbabq_kdb_ k\hckl\Z ©Ijb\be_]bjh\Zggucª hagZqZ_l ©emqrbcª ©[he__ \ukhdbc q_f m hklZevguoª
<hijhk § 8 Obfbq_kdb_ k\hckl\Z f_lZeeh\
AZibr_f mjZ\g_gb_ j_Zdpbc h[jZah\Zgby `_e_aghc hdZebgu
↑
²ij_^klZ\ey_3Fel kh[hc+ 4H2kfO =kvFe^\mo3O4 + hdkb^h\4H2 (1))H2
Fe3OIhwlhfm4 mjZ\g_gb_ j_Zdpbb fh`gh mkeh\gh ij_^klZ\blvFe2O3. \ \b^_ ^\mo mjZ\g_gbc b ^ey dZ`^h]h khklZ\blv mjZ\g_gb_ we_dljhggh]h [ZeZgkZ
Fe + H2O = FeO + H2↑
2Fe + 3H2O = Fe2O3 + 3H2↑
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3Fe + 4H2O = |
FeO Fe2O3 + 4H2↑ |
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Hl\hj G e
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<hijhk 2
S_ehqgu_ b s_ehqgha_f_evgu_ f_lZeeu hq_gv Zdlb\gu b j_Z]bjmxl ijZdlbq_kdb kh \k_f k q_f khijbdZkZxlky
GZijbf_j gZ \ha^mo_ wlb f_lZeeu e_]dh hdbkeyxlky ?keb wlb f_lZeeu ojZgblv ih^ keh_f d_jhkbgZ d dhlhjhfm hgb bg_jlgu lh fh`gh m[_j_qv hl g_gm`guo \aZbfh^_ckl\bc Eblbc ² kZfuc e_]dbc ba f_lZeeh\ Hg e_]q_ d_jhkbgZ b \ hlebqb_ hl ^jm]bo f_lZeeh\ \kieu\Z_l \ g_f ihwlhfm _]h ojZgyl \ \Za_ebg_
KZ<hijhk
+ 12HNO3 = 5Ca(NO3)2 + N2↑ + 6H2O.
−
<hijhk
Ih ijZ\bem dhlhjh_ ]eZkbl qlh f_lZeeu klhysb_ \ jy^m gZijy`_gby e_\__ \h^hjh^Z \ul_kgyxl _]h ba jZkl\hjh\ dbkehl \h^hjh^ ijb j_Zdpbb k\bgpZ k jZkl\hjhf k_jghc dbkehlu ^he`_g ihemqblvky Gh ^Zggh_ ijZ\beh kh[ex^Z_lky _keb \ j_Zdpbb f_lZeeZ k dbkehlhc h[jZam_lky jZkl\hjbfZy khev Z 3E62 g_jZkl\hjbfZy khev Ihwlhfm \ kemqZ_ k\bgpZ b k_jghc dbkehlu4 — ijZ\beh g_ ^_ckl\m_l b ke_^h\Zl_evgh \h^hjh^ g_evay ihemqblv ijb \aZbfh^_ckl\bb k\bgpZ k jZkl\hjhf k_jghc dbkehlu
<hijhk
4Zn + 5H2SO dhgp = 4ZnSO4 + H2S↑ + 4H2O
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< wlhc j_Zdpbb pbgd ijhy\ey_l \hkklZgh\bl_evgu_ k\hckl\Z
<hijhk
= :]jbdhe \ k\h_c dgb]_ bf_e \ \b^m ibjhf_lZeemj]bx Ibjhf_lZeemj]bq_kdb_ ijhp_kku \dexqZxl h[`b] ijb wlhf kh^_j`Zsb_ky \ jm^Zo kh_^bg_gby f_lZeeh\ \ qZklghklb kmevnb^u i_j_\h^ylky \ hdkb^u Z k_jZ m^Zey_lky \ \b^_622 gZijbf_j
18
2CuS + 3O2 2CuO + 2SO2↑; |
Cr2O3 |
+ 2Al Al2O3 + 2Cr. |
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AZl_f hdkb^u i_j_\h^ylky \ qbklu_ f_lZeeu iml_f Zfhghl_jfbb |
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Wdheh]bq_kdb [he__ [_ahiZk_g [Zdl_jbZevguc f_lh^ ihemq_gby f_^b |
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<hijhk |
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S_ehqgu_ b s_ehqgha_f_evgu_ f_lZeeu g_evay ihemqblv |
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]b^jhf_lZeemj]bq_kdbf f_lh^hf ihlhfm qlh ^Zgguc f_lh^ |
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hkgh\Zg gZ \u^_e_gbb f_lZeeh\ ba jZkl\hjZ ih^ ^_ckl\b_f |
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we_dljbq_kdh]h lhdZ : _keb fu ba jZkl\hjZ \u^_ebf s_ehqghc |
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f_lZee \ qbklhf \b^_ lh hg kjZam `_ [m^_l \aZbfh^_ckl\h\Zlv k |
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\h^hc h[jZamy ]b^jhdkb^ |
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1) 2PbS + 3O2 = 2SO2↑ + 2PbO, |
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2) PbO + CO = Pb + CO2↑. |
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→ |
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4FeS2 + 11O2 = 2Fe2O3 + 8SO2↑; |
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2SO2 + O2 = 2SO3; |
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SO3 + H2O = H2SO4; |
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Fe2O3 + 3C |
= 2Fe + 3CO↑. |
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>ZghP]hj ihj |
l d] ω(Cu2S) = 20 %, W = 90 % |
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GZclb: m(Cu) |
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J_r_gb_ GZc^_f kdhevdh&X26kh^_j`blky \ ]hjghc ihjh^_ |
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m(Cu2S) = m ]hj ihj ω(Cu2S) = 1,2 108] 0,2 = 2,4 107] |
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GZc^_f kdhevdh qbklhc f ^b fh`gh ihemqblv l hj_lbq_kdb ba |
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Cu2S: |
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ml_hj(Cu) = m(Cu2S) ω&X\ &X2S) = m(Cu2S) |
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= 2,4 107 |
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= 1,92 107 ] |
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GZc^_f kdhevdh qbklhc f_^b ihemqbeb ijZdlbq_kdb |
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mijZdl(Cu) = ml_hj(Cu) W = 1,92 107 0,9 = 1,728 107 ] |
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Hl\_l: m(Cu) = 17,28 l |
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19
<hijhk
§ 10 Dhjjhaby f_lZeeh\
MjZ\g_gb_ j_Zdpbb dhjjhabb f_^b
<hijhk |
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S_ehqgu_ b s_ehqgha_f_evgu_ f_lZeeu fh]ml j_Z]bjh\Zlv k H2, |
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N2, H22b KH2 \oh^ysbfb \ khklZ\ \ha^moZ |
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4Li+O2 = 2LiO2; |
6Li + N2 = 2Li3N; D H2 D2H2; |
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Li2O+CO2=Li2CO3; |
2Na+O2=Na2O2; |
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2Na2O2+2CO2=2Na2CO3+O2↑; |
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Ca(Mg, Ba) + O2 = CaO (MgO, BaO); |
CaO + CO2 = CaCO3. |
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G_j`Z\_xsZy klZev ²kieZ\ kh^_j`Zsbc ^h ojhfZ % |
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gbd_ey Ihwlhfm ^ey \uieZ\db d] g_j`Z\_xs_c klZeb gm`gh |
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\aylv |
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P &U PkieZ\Z ω&U d] d] |
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P 1L PkieZ\Z ω1L d] d] |
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P )H PkieZ\Z ω&U d]±d]±d] d] |
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Hl\_lPKU d]P 1L d]P )H d] |
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< < FZydh\kdbc ]h\hjbl h[ hpbgdh\Zgghf `_e_a_ |
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>mfZx \k_f ohjhrh ba\_klgh qlh lZdh_ ]Zev\Zgbq_kdbc we_f_gl |
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>\Z kh_^bg_gguo f_`^m kh[hc we_dljh^Z himkdZxl \ jZkl\hj |
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we_dljheblZ gZ h^ghf we_dljh^_ \ j_amevlZl_ H<J ijhbkoh^bl |
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hkZ`^_gb_ f_lZeeZ gZ ^jm]hf gZh[hjhl jZkl\hj_gb_ LZd`_ |
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ihemqbehkv b k dhjZ[e_f fhjkdZy \h^Z ku]jZeZ jhev jZkl\hjZ |
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we_dljheblZ :exfbgb_\uc dhjimk b f_^gu_ aZde_idb ²jhev |
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we_dljh^h\ \ j_amevlZl_ f_lZeebq_kdbc Al i_j_oh^bl \ Al3+, gZ |
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f_^ghf dhjimk_ \u^_ey_lky \h^hjh^ |
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2H+ + • |
, |
Al0±• Al3+. |
LZdbf h[jZahf f lZeebq_kdbc dhjimk gZ r\Zo gZqZe jZkl\hjylvky b dhjZ[ev mlhgme
20
