- •Chemistry 5b072600, 5b073300 (300 tests)
- •1. The elementary object is …
- •Number of equivalents of substance a per 1 liter of solution
- •Mass of substance a to the total mass
- •There is no unit
- •There is no unit
- •There is no unit
- •If values s are given in the table.
- •172. Using standard warmth of combustion of substances to calculate thermal effect of reaction at 298к
- •167. Using standard warmth of combustion for substances to calculate thermal effect of reaction
- •Values are resulted in the table:
- •Values are resulted in the table:
Values are resulted in the table:
Substance |
|
ZnCl2 |
–478,2 |
CuCl2 |
–262,3 |
-215,9
740,5
–903,6
904,2
370,2
177. What quantity of warmth will be allocated at dissolution of 200 g. copper oxide in hydrochloric acid at the thermo chemical reaction: CuO+2HCl = CuCl2+H2O - 63, 6 kJ.?
160
140
120
180
110
178. To calculate quantity of warmth this will be absorbed at receiving of 12 g. of oxygen at the thermo chemical reaction: 2KNO3= 2KNO2+O2+ 255 kJ.
95,6
80,4
75,6
69,6
59,6
179. What quantity of warmth will be allocated at combustion of 4, 48 l. (n.c.) methane at the thermo chemical reaction:
CH4+2O2 = CO2+2H2O-878 kJ?
175,6
150,3
140,6
130,6
165,3
180. Indicate condition parameters:
U,H
U,Q
Q,A
P,W
A,S
181. Thermal effect at formation of one mole of substance is called as warmth …
Formations
Combustion
Thermal effect
Dissolution
Crystallisation
182. Criterion of course of chemical process at entropy and volume constancy is
U;
H;
G;
A;
S;
183. Criterion of direction of chemical process at P=const, S=const is …
H;
A;
G;
U;
S;
184. Criterion of direction of chemical process at V=const, T=const is …
A;
U;
S;
G;
H;
185. At what values of thermodynamic potentials process goes spontaneously:
ΔG<0
ΔG>0
ΔH>0
ΔH<0
ΔA>0
186. Criterion of direction of chemical process at P=const, T=const is …
G;
A;
U;
S;
H
187. Energy of Gibbs in spontaneous process …
Decreases;
Increases;
Remains on the same place;
All answers are correct;
All answers are not correct;
188. Indicate changes of Gibbs's energy:
G=H-TS;
G=-HTS;
G=H+TS;
G=H-U;
G=H / TS;
189. Mendeleyev-Klayperon equation for 1 mole ideal gas:
190. Sedimentation, colour changing at adding of electrolyte to colloid are signs …
A) Coagulation;
B) Flocculation;
C) Stabilization;
D) Dialysis;
E) Osmosis
191. Passing through disperse system, light is absorbed, reflected or dissipated by particles. Dispersion of light most typical for systems …
colloid;
harddispers;
molecular;
ionic;
macroheterogeneous.
192. A coagulation rule: among organic ions coagulate action increases with increase... abilities.
sorb;
diffuse;
absorb;
electro kinetic;
electro foretic
193. The dispersive environment - gas, a disperse phase - a liquid.
Fog;
emulsion;
suspension;
solid sol;
smoke;
194. The dispersive environment - gas, a disperse phase – solid substance.
smoke
solid sol;
solid foam
suspension
fog
195. The dispersive environment - liquid, a disperse phase - a liquid.
emulsion ;
sol;
fog;
smoke;
suspension;
196. The dispersive environment - liquid, a disperse phase - solid substance.
suspension;
smoke;
dust;
fog;
emulsion;
197. The dispersive environment -solid, a disperse phase - solid.
solid sol;
suspension;
smoke;
dust;
fog;
198. The dispersive environment - liquid, a disperse phase - solid.
without name;
sol;
smoke;
D)fog;
E)suspension;
199. The dispersive environment - gas, a disperse phase - liquid.
without name;
fog;
smoke;
dust;
sol;
200. The dispersive environment - solid, a disperse phase - gas.
solid foam;
smoke;
dust;
fog;
suspension;
201. The dispersive environment - liquid, a disperse phase - gas.
foam ;
smoke;
dust;
fog;
sol;
202. Faraday and Tindal have described the phenomenon observed at missing of light through colloid solution, named...
Opalescence,
Extinction,
Diffraction,
Reflexion ,
Absorption
203. Faraday and Tindal have described the phenomenon observed at missing of light through colloid solution, named...
Opalescence,
Extinction,
Diffraction,
Reflexion ,
Absorption
204. The system consisting of several phases is called:
Heterogeneous,
homogeneous,
uniform,
phase, u
nicomponent
205. The solid substance on which surface there is an adsorption, is …
adsorbent;
adsorbate;
adsorbtive;
sorbat;
sorbent;
206. Spontaneous transition of substance from volume of environment in a phase is named...
Adsorption;
hemosorption;
desorption;
sorption;
Absorption;
207. Absorption of substance from the environment by volume of a phase of disperse system name …
Absorption,
Adsorption,
hemosorption,
desorption,
sorption
208. Unilateral diffusion of the dispersive environment in porous systems is called:
osmosis,
electrophoresis,
Dialysis,
electroocmosis,
Electrodialysis.
209. Directed moving of particles of disperse phase under the influence of the enclosed potential difference.
Electrophoresis;
Electrodialysis,
Electroosmosis;
Dialysis;
Electrolysis
210. The phenomena of electrophoresis and electroosmosis is ... in a science and the technician.
Useful,
Harmful,
Indifferent,
Negative,
useless
211 The general formula of alkanes
A) CnH2n+2
В) CnH2n
С) CnH2n-2
D) CnH2n-6
Е) CnH2n-4
212 The general formula of alkenes
A) CnH2n
В) CnH2n+2
С) CnH2n-2
D) CnH2n-6
Е)CnH2n-4
213 The general formula of alkadienes
A) CnH2n-2
В) CnH2n-6
С) CnH2n
D) CnH2n-4
Е) CnH2n+2
214. The general formula of alkynes
A) CnH2n-2
В) CnH2n-6
С) CnH2n
D) CnH2n-4
Е) CnH2n+2
215. Indicate alkanes: 1) С6Н12 2) С5Н12 3) С4Н10 4) С2Н2 5) С4Н8
A) 2,3
В) 1,2
С) 3,4
D) 4,5
Е) 1,5
216. Indicate alkenes: 1) С3Н8 2) С4Н8 3) С4Н10 4) С5Н10 5) С2Н2
A) 2,4
В) 1,5
С) 2,3
D) 1,3
Е) 4,5
217. Indicate alkynes: 1) С3Н4 2) С6Н12 3) С5Н10 4) С4Н6 5) С4Н8
A) 1,4
В) 2,3
С) 1,2
D) 2,5
Е) 3,5
218. Determine the class of the compound: СН3 - CH2 - CН2 - CH2 - OH
A) alcohol
В) ester
С) ketone
D) aldehyde
Е) ether
219. Determine the class of the compound: СН3 CH2 О CН2 CН3
A) ether
В) ester
С) ketone
D) aldehyde
Е) alcohol
220.
Determine the class of the compound:
A) ketone
В) acid
С) ester
D) aldehyde
Е) ether
221. Determine the class of the compound: СН3 CH2 CН2 CН2 COOH
A) carboxylic acid
В) ester
С) ketone
D) aldehyde
Е) alcohol
222.
Determine the type of reaction:
A) substitution
В) addition
С) decomposition
D) oxidation
Е) reduction
223.
Determine the type of reaction:
A) substitution
В) addition
С) decomposition
D) oxidation
Е) reduction
224.
Determine the type of reaction:
A) addition
В) substitution
С) decomposition
D) oxidation
Е) reduction
225.
Determine the type of reaction: СН3
СH
= CH
СН3
+ H2O
A) addition
В) substitution
С) decomposition
D) oxidation
Е) reduction
226. Alkane with octane number 0
A) heptane
В) octane
С) hexane
D) propane
Е) pentane
227. Alkane with octane number 100
A) 2,2,4-trimethylpentane
В) octane
С) hexane
D) heptane
Е) pentane
228. Reagents interacting with alkanes:
1. Cl2(hn) 2. HNO3+H2O 3.NaOH 4. Br2 +HOH 5. HOH
A) 1,2
В) 4,5
С) 3,4
D) 3,5
Е) 1,4
229. Reagents interacting with alkanes:
1.NaOH 2. Br2 +HOH 3. HOH 4. Cl2(hn) 5. HNO3+H2O
A) 4,5
В) 1,2
С) 3,4
D) 3,5
Е) 1,4
230. Reaction condition for nitration of alkanes:
A) HNO3 diluted
В) HNO3 concentrated
С) HNO3+ H2SO4
D) NO2
Е) N2O4
231. HNO3 (diluted) is used for …
A) nitration of alkanes
В) oxidation of alkanes
С) decomposition of alkanes
D) conversion of alkanes
Е) radical substitution
232. Bromic water is decoloured by compounds:
1) alkenes 2) alkanes 3) dienes 4) alcohols
A) 1,3
В)1,2
С) 2,3
D) 3,4
Е) 2,4
233. Bromic water is decoloured by compounds:
1) alkenes 2) alkanes 3) dienes 4) alcohols
A) 1,3
В)1,2
С) 2,3
D) 3,4
Е) 2,4
234.
Name the final product:
A) acetylene
В) ethylene
С) ethane
D) propyne
Е) propylene
235. The author of nitrate reaction for alkanes:
A) Konovalov
В) Kolber
С) Zaitsev
D) Wurtz
Е) Butlerov
236. Synthetic high-molecular substances:
Polyethylene;
Rubber;
Fibers;
Nucleinic acids;
polysaccharide
237. Electronegativity is an ability of atom...
A) to attract electrons
B) to delocalized electrons
C) to distribute electrons
D) to give electrons
E) to push away electrons
238. Characteristic of covalence bond
A) Polarizability
B) Length of bond
C) Electronic density
D) Hardness of bond
E) Electro negativity
239. Specify, what sublevel is filled after 4s
А) 3d
В) 4p
С) 3S
D) 5S
Е) 4f
240. Specify the number of electrons in atom of aluminum
А) 13
В) 27
С) 14
D) 11
Е) 10
241. What of metals refers to d - elements?
А) Fe
В) Na
С) Ca
D) Ba
Е) Li
242. Specify the number of electrons of oxygen atom
А) 8
В) 16
С) 32
D) 2
Е) 18
243. What formula reflects the total number of electrons in energy level?
А) N=2n2
В) N=2n
С) N=n
D) N= √2n
Е) N=2√n
244. Name the element that has an electronic formula...3s23p3
А) P
В) Al
С) O
D) S
E) K
245. In what group are alkaline metals in D.I.Mendeleyev table located?
А) I A
В) II A
С) III A
D) VI A
Е) VII A
246. In what group is alkaline earth metals are located in the table of D.I.Mendeleyev?
А) II A
В) I A
С) III A
D) VII A
Е) VIII A
247. In what group are halogens in D.I.Mendeleyev's table located?
А) VI A
В) VII A
С) I A
D) II A
Н) VII A
248. Specify the number of neutrons for an atom of potassium
А) 20
В) 19
С) 39
D) 21
Е) 5
249. What electronic formula corresponds to atom of oxygen?
А) 1S22S22p4
В) 1S22S22p3
С) 1S22S22p5
D) 1S22p6
Е) 1S22S22p1
250. Specify the maximum amount of electrons at the first energy level
А) 2
В) 18
С) 8
D) 32
Е) 38
251. Number of the electrons on the outer energy p-sublevel of atom of chlorine is equal to
А) 5
В) 7
С) 3
D) 6
Е) 1
252. How many power levels has the atom with a serial number 8
А) 3
В) 1
С) 2
D) 4
Е) 8
253. Specify the maximum number of electrons on p-orbital
А) 6
В) 8
С) 2
D) 10
E) 5
254. How many elements in the fourth period of periodic system?
18
10
22
32
8
255. What the line of elements is presented in increasing order of nuclear radius?
О, S, Se, Те
С, N, О, F
Na, Mg, Al, Si
J, Br, Се, F
He, В, Xe, Кr
256. How many of energy orbitals exist for chemical elements?
4
3
2
5
6
257. What is the electronic formula of Al
А) 1S22S22p63S23p1
В) 1S22S22p63S23p3
С) 1S22S22p63S23p6
D) 1S22S22p63S23p0
Е) 1S22S22p63S1
258. What sublevel is filled after 4S
А) 3d
В) 4p
С) 3p
D) 4d
Е) 4f
259. What sublevel is filled in atoms after the sublevel 5s?
А) 4d
В) 4p
С) 4f
D) 5p
Е) 6s
260. The electronic formula of atom is 1S22S22p63S23p64S23d6 . What element is it?
А) Fe
В) Mn
С) Ca
D) Ni
Е) Pb
261. What maximum number of electrons could the atom contain in an electronic level n=4
А) 32
В) 2
С) 8
D) 18
Е) 6
262.
Indicate
the simple substances:
O2,
,
,
,
С2Н2,
Н2O2,
H2S,
H2SO4,
NaCI
,
,
263. Types of chemical reactions according to the mechanism of interaction
neutralizations, redox reactions, precipitations, complexations
connections, decompositions, replacements, exchanges
convertible and irreversible
direct and return
exothermic and endothermic
264. The basis of the neutralization is the reaction:
Н + + OH- → Н2О
Ва2 + + СО32- → ВаСО3
Вr2 + 2е → 2Br--
Cu2 + + 2OH- → Cu (OH) 2
Ag + + CI- → AgCI
265. What element forms amphoteric oxides?
А) Al
В) Na
С) Ca
D) Mg
Е) Ba
266. Specify amphoteric oxides
А) Al2O3;ZnO
В) CuO;Na2O
С) ZnO;CO2
D) Na2O;Fe2O3
Е) FeO;P2O5
267. Specify the acid oxides
А) CO2;P2O5
В) CaO;SO3
С) P2O5;Fe2O3
D) Al2O3;K2O
Е) ZnO;CrO3
268. Specify not salt-forming oxides
А) CO; NO
В) CO2; SO3
С) N2O; P2O5
D) Na2O; SiO
Е) SO3; SO
269.
To define the base oxides ВеО,
,
ВеО,
,
ВеО,
ВеО,
270.
To define the acidic oxides: Na2O,
СоО,
F
,
MnO2,
BaO, S
,
Si
SO2, SiO2,
Na2O, BaO,
CoO, SO2,
MnO2, Na2O ,
СоО, BaO
271.
To define the one-basic acids: Н3РO4,
HCI,
H2MnО4
272.
To define the two-basic acids:
,
273.
To
define the three-basic acids:
,
H3PО4,
,
, H3PО4
HJ,
H3PО4,
274.
Specify
strong acid:
1
5
2
3
4
275.
Specify
strong acids: H2S04,
H2S,
HJ, H2SО3.
HCN, H2C
,
HCI
H2SО4, HJ, HCI
H2S, H2C , H2SО4
HJ, HCN, H2C ,
H2SО3, H2S, HJ
H2SО4, HCN, HCl
276. Specify weak acids: CH3COOH, НСlO3, H2CO3, HN O2, HBr, HJ, НClO4
C
COOH,
C
,
HNО2HCI . HCI
.
HN
C COOH, HBr, HJ
C , HJ, НClO3
НClO4, HN , C COOH
277.
The
strongest oxygen containing chlorine acid:
HCl
HCl
HClO
HCl
HCl
278. What hydroxides shows amphoteric character
А) Al(OH)3
В) NaOH
С) Ca(OH)2
D) Mg(OH)2
Е) KOH
279.
Define
oxidation degree of nitrogen:
N
N2H4,
NH2OH
-3,-2,-I
2; I; 3
-l,+2,+3
0, +2, -3
-2,-1,0
280. Define oxidation degree of sulfur: SО2, H2S, Na2SО3, CS2, H2SО4
+4,-2, +4, +4, +6
+2,-4, +2,-4,-4
+2,-2, +4, -4,+6
+2,-2,-4,+4, -6
+4, +2,-4,+2,-4
281.
Define
oxidation degree of Мn:
МnО,
+2, +4, +3,+7
+2, -2, +4, +6
-2, +2,-4,+7
+2,-4,+4, -7
+2, +4, -6, -7
282.
In
what compounds
nitrogen
has oxidation degree +5
283. In what compounds chromium has oxidation degree +6
1)
;2)
С
Оз;
3) Na
4)
5) Cr
;
6)
1,5
3,5
4,6
1,2
5,4
284.
In
what compounds
manganese has oxidation degree +7
285. Characteristic degree of oxidation for copper: +1, +2, +3, +4, +6
+2
+4
+3
+1
+5
286. Maximum degree of oxidation for nitrogen
А) +5
В) +3
С) +1
D) 0
Е) +6
289. Define the degree of oxidation of bromine in bromide of potassium
А) -1)
B) +1
С) +7
D) +5
E) -3
290. Define the degree of oxidation of sulphur in Na2SO4
А) +6
В) -6
С) +4
D) -4
Е) 2
291. The charge of the proton is equal to
А) +1
В) 0
С) -1
D) 1,6
Е) 6,02×1023
292. Specify metal with valence 3
А) Al
В) Ca
С) Mg
D) Ag
Е) Zn
293. Specify the chloride-ion
А) Cl-
B) Cl2-
С) Cl02
D) Cl4-
E) ClO-4
294. Specify sulfate - ion
А) SO2-4
В) SO-4
С) SO3-4
D) HSO2-4
Е) HS-
295.
To define coordination numbers of forming complexes in compounds:
K
,
2, 6, 6
1, 4, 3
1, 5, 3
0, 3, 3
1, 4, 3
296.
To define a charge of forming complex in compound
+2, +3
+1, +2
+1, -1
+2, +5
+1, +6
297. What is the type of reaction H2SO4+ 2NaOH =Na2SO4+ 2Н2O:
I) neutralization; 2) replacement; 3) decomposition; 4) addition; 5) oxidation-reduction?
1
3
4
2
5
298. What reactions belong to the oxidation-reduction?
2.
;
3.
;
4. Fe+S=FeS
2, 4
1, 3
2, 3
1, 4
2, 1
299.
What is the type of reaction:
?
Disproportion
Neutralization
Precipitate
Decomposition
Exchange
300. Oxidizer:
Accepts electrons;
Gives electrons;
Replaces protons;
Reduces enthalpy;
Absorbs warmth.
301. Reducer:
Gives electrons;
Accepts electrons;
Replaces protons;
Reduces enthalpy;
Absorbs warmth.
302.
Oxidizer for the given reaction:
,
,
,
,
303. Reducer for the given reaction: 4NH3+3O2=2N2+6H2O
N-3
H+1
O0
N0
O-2
304.
To specify the sum of coefficients for reaction:
10
8
6
2
4
305.
To specify the sum of coefficients for reaction:
А)20
Б)12
В)10
Г)14
Д)11
306.
To specify the sum of coefficients for reaction: K2S
+K2Cr2
+H2SО4
S + K2S04
+ Cr2
(SО4
+
А) 26
Б) 20
В) 24
Г) 18
Д)22
307.
To specify the sum of coefficients for reaction:
+
A.7
B.8
C.6
D.5
E.3
308.
To specify the sum of coefficients for reaction:
13
10
9
7
14
309.
To specify the sum of coefficients for reaction:
19
17
14
21
13
310.
To specify the sum of coefficients for reaction:
7
6
4
8
5
311.
To specify the sum of coefficients for reaction:
22
20
18
16
14
312.
To specify the sum of coefficients for reaction:
→
10
8
6
4
5
313.
To specify the sum of coefficients for reaction:
+
+
→Cr
+
+
O
A) 14
B) 12
C) 10
D) 8
E) 6
314. pH of solution calculates according to the formula:
pH = 14 - pOH
pH = 14 + pOH
pH = KgC + 10
pH = N/n
pH = n/N
315. The hydroxyl indicator of environment is equal:
pH = [H+][OH-]
рОН = -lg[H+]
[pОH = - lg[ОH-]
H2O] = -lg[OH-]
pOH= -lg[H+][OH-]
316. To specify an alkaline solution:
[H+] = 10-12
[H+] = 10-7
[ОH-] = 1031
[ОH-] = 10-3
[H 2О] = 107
317. To specify a neutral solution:
H+] = [OH-]
[H+] > [OH-]
[H+] < [OH-]
pH = 12
pH = 17
318. Electrolysis is:
oxidation-reduction process;
disintegration of a molecule of electrolit to ions;
process of association of ions;
movement of electrons around of nucleus;
process of molecule dissociation.
319. Cathode is an electrode at which there is a process:
Reduction of cations;
Oxidation of anions;
Disintegration of molecules;
Association of ions;
Changing of oxidation degree of an element.
320. Anode is an electrode at which there is a process:
Oxidation of anions;
Reduction of cations;
Disintegration of molecules;
Association of ions;
Changing of oxidation degree of an element.
321. Electrolyte of the lead accumulator is the solution of:
H2SO4
H2O
H3PO4
HF
HCI
322. Inhibitor is:
diminish of corrosion
corrosion accelerator
protector
accumulator
galvanic cell.
323. Faraday number is equal:
96500
73500
760
101
83100
324. Potential of a standard hydrogen electrode is equal:
0
1
2
5
9
325. To inert anodes belong:
graphite, platinum
zinc, copper
chrome, manganese
zinc, chrome
iron, zinc
326. To active anodes belong:
copper
platinum
neon
graphite
plastic
327. At electrolysis of NaCl solution at the anode it is allocated:
chlorine
sodium
oxygen
hydrogen
water
