- •Choose the correct range of acidity increase for the following compounds.
- •Formic acid
- •*Formic acid
- •Choose the correct range of acidity increase for the following compounds.
- •What is the identity of the intermediate (a) and the end-product (b) in the
- •To which group of lipids do terpenes belong?
- •Which group of compounds does borneol belong?
- •Which group of compounds does α-pinene belong?
- •Determine what compound will form after the glucose oxidation by Felling reagent:
- •What reaction do monosaccharides in the cyclic form?
cyclopolyene
bicyclic aldehyde
cycloalkane
aliphatic ketone
*monocyclic diene
Terpenes are unsaturated compounds with the formula (C5H8)n, where n - number of isoprene fragments. What is the name of terpenes type with п = 8?
*tetraterpenes
triterpenes
diterpenes
sesquiterpenes
monoterpenes
Terpenes are unsaturated compounds with the formula (C5H8)n, where n - number of isoprene fragments. What is the name of terpenes type with п = 6?
tetraterpenes
*triterpenes
diterpenes
sesquiterpenes
monoterpenes
To which group of lipids do terpenes belong?
phospholipids
waxes
fats
*isoprenoids
prostaglandins
Which group of compounds does borneol belong?
cycloalkane
*bicyclic alcohol
polycyclic polyene
bicyclic ketone
aliphatic alcohol
Which group of compounds does α-pinene belong?
*bicyclic alkene
bicycles polyene
bicyclic alkyne
aromatic hydrocarbon
monocyclic alkene
Terpenes are unsaturated compounds with the formula (C5H8)n, where n - number of isoprene fragments. What is the name of terpenes type with п = 4?
tetraterpenes
triterpenes
*diterpenes
sesquiterpenes
monoterpenes
Terpenes are unsaturated compounds with the formula (C5H8)n, where n - number of isoprene fragments. What is the name of terpenes type with п = 3?
tetraterpenes
triterpenes
diterpenes
*sesquiterpenes
monoterpenes
Terpenes are unsaturated compounds with the formula (C5H8)n, where n - number of isoprene fragments. What is the name of terpenes type with n = 2?
tetraterpenes
triterpenes
diterpenes
sesquiterpenes
*monoterpenes
Choose the correct reaction scheme of oxyproline with hydrochloric acid.
*
Choose the correct reaction scheme of histidine with iodo methane.
*
Which monosaccharide is the part of RNA?
arabinose
fructose
glucose
deoxyribose
*ribose
What are the products of adenosinemonophosphoric acid complete hydrolysis?
three molecules of phosphoric acid and adenine
two molecules of phosphoric acid, deoxyribose and adenine
*one molecule of phosphoric acid, ribose and adenine
one molecule of phosphoric acid and adenine
two molecules of phosphoric acid and adenine
Choose peptide-group among the listed below.
*
Which bond is used for construction of primary structure of protein?
coordinative
semi polar
*peptide
ionic
hydrogen
Which of the following reaction occurs on the aryl moiety of phenylalanine molecule?
*
Which of the following monosaccharides is the part of DNA?
mannose
ribose
glucose
*deoxyribose
fructose
Choose the acidic amino acids among the listed below.
*
The bond of which type plays the essential role in the nucleobase pairing?
semi polar bond
ionic bond
hydrophobic interactions
*hydrogen bond
non-polar covalent bond
Which of the following acids forms γ-lactame of the structure listed below?
5– aminohexanoic acid
3–aminopropanoic acid
5– aminohexanoic acid
*4-aminobutanoic acid
4–aminohexanoic acid
Which of the following amino acids will form crotonic acid when heated?
*beta-aminobutyric acid
γ-glutamic acid amide (glutamine)
Choose the amino acid which forms the 3,6-dimethyl-2,5-dioxopiperazine when heated.
*
Which of the following reactions can be used for quantitative analyses of α-amino acids?
*
With which of the following reagents 3-aminobutanoic acid will undergo dezamination reaction?
*
Choose the reaction of oxidative dezamination which proceeds in the human body.
*
Choose the correct scheme of α-aminoisovaleric acid (valine) transformation:
*
Which bond plays the essential role in formation of spiral secondary structure of proteins?
hydrophobic interactions
semipolar
peptide
ionic
*hydrogen
Among the listed below choose α-amino acids.
*
Choose the structure of ascorbic acid (vitamin C):
*
The interaction of cellulose with excess of acetanhydride in the presence of H2SO4 (catalyst) leads to formation of:
cellulose sulfate
*cellulose triacetate
cellulose xanthogenate
cellulose diacetate
cellulose acetate
What is the product of reaction of cellulose with excess mixture of nitric and sulfuric acids?
cellulose disulfate
*cellulose trinitrate (pyroxiline)
cellulose sulfate
cellulose dinitrate
cellulose mononitrate
Choose the name of the following disaccharide.
*
Choose the product of interaction of β-cellobiose with excess of ¬³¬¯3І.
*
Which is the end-product of acidic hydrolysis of cellulose?
α-lactose
β-maltose
D-fructofuranose
*D-glucopyranose
D- galactopyranose
Starch consists of amylose and amylopectine which can be hydrolyzed by enzymes to D-glucose. Choose the correct scheme of starch hydrolysis.
*
What is the systematic name of sucrose?
*
What does symbol «D» in the name of D-(+)glucose means?
*the relative configuration of C5 atom
the relative configuration of C4 atom
the relative configuration of C2 atom
levorotatory isomer
dextrorotatory isomer
D-Glucose in the sodium hydroxide solution in the course of time forms the mixture of D-glucose, D-mannose and D-fructose. What is the name of these transformations?
Walden inversion
anomerization
cyclization
*epimerization
mutarotation
Amylopectine (the insoluble in water fraction of starch) is the branched polymer, which consists of:
*
Choose the structure of alfa -D-galactopyranose?
*
Which of the following reagents will form osazones with monosaccharides?
semicarbazide
hydrazine
*phenylhydrazine
hydroxylamine
ammonia
What does the symbol “-“ in the name L-(-)-glucose means?
the relative configuration of С2 atom
the relative configuration of С5 atom
dextrorotatory isomer
*levorotatory isomer
the relative configuration of С4 atom
When D-glucose is treated with sodium hydroxide solution for a few days it forms the mixture of:
D– glucose, D– galactose and D– fructose
D– glucose, D–galactose and D– mannose
*D– glucose, D– mannose and D– fructose
D–glucose and D–mannose
D–glucose and D–fructose
What is the product of D-fructose oxidation with nitric acid?
D–galacturonic acid
*D–arabinaric acid
D–mannitol
D–glucaric acid
D–gluconic acid
In the crystals the molecules of monosaccharides are in the:
enolic hydroxyl
endiol form
in all possible tautomeric forms
acyclic form
*cyclic form
Choose the structure of β-D-galactopyranose?
*
Choose the structure of β-D-ribofuranose?
*
D-glucose and D-mannose are epimers because:
have the different configuration of the fifth carbon atom
are the members of the same stereochemical range
have the different number of chiral carbon atoms
*have the different configuration of the second carbon atom
have the equal number of chiral carbon atoms
How many asymmetric carbon atoms (chiral C atoms) does the following monosacharide have?
five
four
*two
three
one
How many stereoisomers does the following aldohexose have?
eight
thirty two
*sixteen
four
eight
The mutarotation is caused by:
have the equal number of chiral carbon atoms
inversion of configuration of the cyclic forms of monosacharides
*equilibrium of tautomeric forms conversion in the solution
epimeric transformations of monosaccharides
inversion of configuration of the last carbon atom
Which of the following monosccharides are hexoses?
galactose
ribose
arabinose
*mannose
xylose
The change of specific rotation of monosaccharides solution in the course of time is called:
enolic hydroxyl
epimerization
*mutarotation
isomerization
inversion
How many stereoisomers does the following aldopentose have?
