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III. Find words and word combinations that mean the following.

1.  Stock from which material is taken to be fed (charged) into a processing unit.

2. A general term used for low boiling hydrocarbon fractions that are a major component of gasoline. 3. A naturally occurring mixture of hydrocarbons that usually includes small quantities of sulfur, nitrogen, and oxygen derivatives of hydrocarbons as well as trace metals.

4. A low-temperature cracking process used to reduce the viscosity or pour point of straight-run residuum.

5. A number indicating the relative antiknock characteristics of gasoline. 6. A process using sulfuric or hydrofluoric acid as a catalyst to combine olefins (usually butylene) and isobutane to produce a high-octane product known as alkylate.

7. A material that aids or promotes a chemical reaction between other substances but does not react itself.

IV. Summarize the history of refining using the following table.

TABLE 1. HISTORY OF REFINING

Year

Process name

Purpose

By-products, etc.

1862

Atmospheric distillation

Produce kerosene

Naphtha, tar, etc.

1870

Vacuum distillation

Lubricants (original) Cracking feedstocks (1930's)

Asphalt, residual coker feedstocks

1913

Thermal cracking

Increase gasoline

Residual, bunker fuel

1916

Sweetening

Reduce sulfur & odor

Sulfur

1930

Thermal reforming

Improve octane number

Residual

1932

Hydrogenation

Remove sulfur

Sulfur

1932

Coking

Produce gasoline basestocks

Coke

1933

Solvent extraction

Improve lubricant viscosity index

Aromatics

1935

Solvent dewaxing

Improve pour point

Waxes

1935

Cat. polymerization

Improve gasoline yield & octane number

Petrochemical feedstocks

1937

Catalytic cracking

Higher octane gasoline

Petrochemical feedstocks

1939

Visbreaking

Reduce viscosity

Increased distillate,tar

1940

Alkylation

Increase gasoline octane & yield

High-octane aviation gasoline

1940

Isomerization

Produce alkylation feedstock

Naphtha

1942

Fluid catalytic cracking

Increase gasoline yield & octane

Petrochemical feedstocks

1950

Deasphalting

Increase cracking feedstock

Asphalt

1952

Catalytic reforming

Convert low-quality naphtha

Aromatics

1954

Hydrodesulfurization

Remove sulfur

Sulfur

1956

Inhibitor sweetening

Remove mercaptan

Disulfides

1957

Catalytic isomerization

Convert to molecules with high octane number

Alkylation feedstocks

1960

Hydrocracking

Improve quality and reduce sulfur

Alkylation feedstocks

1974

Catalytic dewaxing

Improve pour point

Wax

1975

Residual hydrocracking

Increase gasoline yield from residual

Heavy residuals

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