- •1 Level (6 points)
- •History of the need for building materials
- •Cement production in the Republic of Kazakhstan
- •The history of obtaining and production cement
- •Economics of cement production
- •Determination of clinker, cement and additives introduced in the grinding
- •The composition of the raw meal. Equations 1-4
- •The composition of the raw meal. Equations 5-9
- •An overview of phase composition and quality phase of clinker
- •Portland cement clinker.
- •Chemical and mineralogical composition alite
- •Chemical and mineralogical composition of belite
- •Phase aluminate
- •Phase Ferrite
- •Other clinker phases
- •The composition and place of origin of the phases in portland cement clinker
- •Analysis of the raw meal, cement and clinker
- •Microscopic research of clinker
- •Recent developments in the use of X-rays
- •Petrographic analysis of clinker
- •Cement production
- •Raw materials and fuels in cement production
- •The raw materials of cement industry
- •Limestone and clay
- •A natural mixture of clay and limestone
- •Waste and their use in the cement industry
- •2 Level (6 points)
- •Mining, processing of raw materials, grinding of raw meal and homogenisation.
- •The blending warehouse of raw materials and its functions.
- •Development of the pile by rotary excavator
- •The process of burning cement clinker. General concepts
- •Chemical reactions during heat treatment of portland cement raw meal (main reaction clinker burning)
- •The dehydration of kaolinite
- •The reactions during the sintering
- •Reaction with cooling
- •Homogeneity of the raw meal
- •The process of burning cement clinker
- •Procedures for burning cement clinker
- •Decarbonizators with upward vertical gas flue.
- •The fuel in cement production
- •Clinker cooler
- •Cooler sf (Smidth-Fuller).
- •Storage of clinker
- •Cement Grinding
- •Milling equipment
- •The fineness of grinding and particle size distribution (grain) composition of the cement
- •Storage, packing, shipment cement to the consumer
- •The granulated blast furnace slag (s)
- •Pozzolan (p, q)
- •Natural pozzolanic additives (р)
- •Natural volcanic pozzolanic additives (q)
- •3 Level (8 points)
- •Fly ash rich in silica (V)
- •Lime ash dust (w)
- •Calcined shale (t)
- •Limestone (l, ll)
- •The quartz dust (d)
- •Small components
- •Calcium sulphate
- •The cement admixture
- •Cement according to standard
- •Physical and chemical properties of cements according to European standard
- •Cements with special properties
- •Well cement
- •Hydration
- •The reaction of silicates (c3s, c2s)
- •Hydration c3s
- •Hydration c2s
- •Reactions of hydration aluminate without participation of sulfates
- •Reactions hydration aluminate with participation sulphates
- •Hydration ferrite (c4af)
- •Taylor Model
- •Model Stark
- •The cement hydration
- •Reaction of the secondary components
- •Hydration of cement containing granulated slag
- •Reactions pozzolanic materials
- •4 Level (8 points)
- •Slowing solidification
- •Structure of a cement stone
- •Building lime
- •The historical and economic situation. Raw material deposits
- •Production and processing of limestone
- •Burning lime
- •Shaft kiln to coke (coal) and gas fuel
- •The rotary tube kiln
- •Counter current regenerative kiln (ggr-kiln)
- •Shaft ring kiln
- •Grinding and shipment of burnt lime
- •Slaked lime
- •The use of lime products
- •The requirements of stst 9179-79 to building lime
- •Gypsum. History and economy
- •Physical and chemical bases of gypsum binders
- •Phases in the system CaSo4 - h2o
- •The crystal structures, double salts, mixed crystals
- •Natural gypsum, natural anhydrite
- •The chemical gypsum
- •Uddg- gypsum
- •Production of calcium sulphate binders
- •Technological processes in the production of calcium sulphate binders
- •Autoclave method for producing α-hemihydrate
- •Gypsum boiling kettle for the production of ß-hemihydrate
- •5 Level (12 points)
- •The high temperature burning of gypsum method (multiphase gypsum) on the grate
- •Properties capable of hardening calcium sulphates
- •Hydration CaSo4-binding
- •Natural -, uusdg - and chemical anhydrite
- •The properties of the treated gypsum building materials
- •Other areas of application
- •The norms, chemical analysis and phase analysis
- •Gypsum Products
- •The requirements of gost 125-79 for the quality of construction gypsum
- •Other inorganic binding materials
- •Alumina cement
- •Production of alumina cement
- •Chemical and mineralogical composition of the alumina cement
- •Areas of use alumina cement
- •Softeners (plasticizers), added during the production concrete
- •Softeners (plasticizers), added to the concrete mix
- •Concrete
- •Mobile concrete plants
- •Concrete for precast concrete elements
- •Self-compacting concrete
- •Building mortar
- •Cement mortar
- •Plaster
- •Cementing deep wells
The history of obtaining and production cement
This material is obtained by mixing finely ground clinker and gypsum. Their equity ratio depends on what brand of cement needed. What is the first component? This mixture of fines of limestone and clay, which as the temperature rises to 1 400-1 500 ° C to melt and begin to "seize" with each other. As a result - the formation of clinker granules. In the next stage of production, they are brought to the "flour" state and mixed with gypsum (until smooth).
cement production scheme
Because of the nature of production, it can be divided into the following stages:
• raw material delivery. Given the cost of transport enterprises for the production of cement is economically advantageous to place the vicinity of clay and limestone mining (major components);
• the process of grinding and mixing fractions;
• firing the cement mass;
• grinding to a powder;
• the addition of gypsum and other substances (if provided by the cement manufacturing technology);
The lion's share of all production costs for cement (up to 75-80%) falls to the clinker.
There are a number of manufacturing technologies. Choosing the best option depends on the quality of raw materials and available in the capacities of the enterprise (primarily for heat treatment of materials).
clinker production methods
They differ in the specifics of the preparation and processing of raw materials.
"Dry"
As the name suggests, that the use of a liquid is not assumed. First, the basic ingredients of the cement are broken into small fractions, triturated, then this is done thorough mixing flour (limestone + clay) with compressed air (with simultaneous drying and adjusting the ratio of share of ingredients). Final stage - calcining the resulting mixture and converting the cement "flour". It can be produced in a rotary kiln, or the mine.
This method is the most cost-effective and is increasingly being used in new or upgraded facilities.
"Wet"
There are several methods of implementing this method of manufacturing cement, which depend on the properties of the components of (primarily of their density). Consider the most commonly used.
Chunks of limestone, coming to the company, rather large. Therefore organized their first crushing (2 - 3 steps) until all fractions are obtained with dimensions not exceeding 10 mm. If necessary, Roller units made further (final) split.
The same raw material preparation technique for the cement is applied to the clay, which is then soaked in the so-called "mash". Humidity resulting slurry can be 65-70%. He served in the "mill", which simultaneously receives and ground limestone. There is a simultaneous additional grinding and mixing clay clinker components.
If used in the production of cement or chalk tuff (soft limestone), the technology is somewhat different. Stirring was further performed with clay in the milling step (a crusher), then soaked weight. The final grinding is performed in "mill".
The resulting mass of not more than 40% moisture, with the help of pumps is supplied to the vertical-type swimming pool, where finally adjusted the percentage of cement components. Next - horizontal pool, from which you are downloading in the kiln.
The final step is the cooling of the mass, and its transformation into a "flour". Then - in the silo for storage of the finished cement.
This method makes it possible to achieve high homogeneity of the product, even in cases where the starting materials are very different in their characteristics (e.g., hardness) or impurities present in them. But there is a drawback - the increased consumption of thermal energy.
Basically, in this way it is organized the production of cement in most of our businesses, since they were built during the Soviet period and were "imprisoned" is on this technique.
"Semi-dry"
After grinding to a fraction the size of no more than 20 mm dried clay and limestone. After the end of the process the moisture level in the material is between 10 - 15%. Preliminary heat treatment of the cement components produced in "Lepol furnaces." The pellets are tray on a tray, through which pass the gases, their warming up to 950 ° C. This allows not only the dry mass, but also reduce the level of carbonation approximately ¼. Thereafter enters the furnace clinker (shaft) for firing. Furthermore - in grinding hopper.
"Combined"
Such a process combines the two techniques ("wet" and "semi-dry"). Prepared in a "mill" sludge with humidity at 40-45% passes through a filter, where it is dehydrated (up to 15- 18%). Next - the mixing of raw materials for cement dust from the gases in the furnace "Lepol". This further reduces the level of the liquid content of 3-5%.
Thereafter, the mass is fed into the rotary kiln, fired, and after the final grinding in a "flour" finished cement is sent to the repository.
