- •1 Level (6 points)
- •History of the need for building materials
- •Cement production in the Republic of Kazakhstan
- •The history of obtaining and production cement
- •Economics of cement production
- •Determination of clinker, cement and additives introduced in the grinding
- •The composition of the raw meal. Equations 1-4
- •The composition of the raw meal. Equations 5-9
- •An overview of phase composition and quality phase of clinker
- •Portland cement clinker.
- •Chemical and mineralogical composition alite
- •Chemical and mineralogical composition of belite
- •Phase aluminate
- •Phase Ferrite
- •Other clinker phases
- •The composition and place of origin of the phases in portland cement clinker
- •Analysis of the raw meal, cement and clinker
- •Microscopic research of clinker
- •Recent developments in the use of X-rays
- •Petrographic analysis of clinker
- •Cement production
- •Raw materials and fuels in cement production
- •The raw materials of cement industry
- •Limestone and clay
- •A natural mixture of clay and limestone
- •Waste and their use in the cement industry
- •2 Level (6 points)
- •Mining, processing of raw materials, grinding of raw meal and homogenisation.
- •The blending warehouse of raw materials and its functions.
- •Development of the pile by rotary excavator
- •The process of burning cement clinker. General concepts
- •Chemical reactions during heat treatment of portland cement raw meal (main reaction clinker burning)
- •The dehydration of kaolinite
- •The reactions during the sintering
- •Reaction with cooling
- •Homogeneity of the raw meal
- •The process of burning cement clinker
- •Procedures for burning cement clinker
- •Decarbonizators with upward vertical gas flue.
- •The fuel in cement production
- •Clinker cooler
- •Cooler sf (Smidth-Fuller).
- •Storage of clinker
- •Cement Grinding
- •Milling equipment
- •The fineness of grinding and particle size distribution (grain) composition of the cement
- •Storage, packing, shipment cement to the consumer
- •The granulated blast furnace slag (s)
- •Pozzolan (p, q)
- •Natural pozzolanic additives (р)
- •Natural volcanic pozzolanic additives (q)
- •3 Level (8 points)
- •Fly ash rich in silica (V)
- •Lime ash dust (w)
- •Calcined shale (t)
- •Limestone (l, ll)
- •The quartz dust (d)
- •Small components
- •Calcium sulphate
- •The cement admixture
- •Cement according to standard
- •Physical and chemical properties of cements according to European standard
- •Cements with special properties
- •Well cement
- •Hydration
- •The reaction of silicates (c3s, c2s)
- •Hydration c3s
- •Hydration c2s
- •Reactions of hydration aluminate without participation of sulfates
- •Reactions hydration aluminate with participation sulphates
- •Hydration ferrite (c4af)
- •Taylor Model
- •Model Stark
- •The cement hydration
- •Reaction of the secondary components
- •Hydration of cement containing granulated slag
- •Reactions pozzolanic materials
- •4 Level (8 points)
- •Slowing solidification
- •Structure of a cement stone
- •Building lime
- •The historical and economic situation. Raw material deposits
- •Production and processing of limestone
- •Burning lime
- •Shaft kiln to coke (coal) and gas fuel
- •The rotary tube kiln
- •Counter current regenerative kiln (ggr-kiln)
- •Shaft ring kiln
- •Grinding and shipment of burnt lime
- •Slaked lime
- •The use of lime products
- •The requirements of stst 9179-79 to building lime
- •Gypsum. History and economy
- •Physical and chemical bases of gypsum binders
- •Phases in the system CaSo4 - h2o
- •The crystal structures, double salts, mixed crystals
- •Natural gypsum, natural anhydrite
- •The chemical gypsum
- •Uddg- gypsum
- •Production of calcium sulphate binders
- •Technological processes in the production of calcium sulphate binders
- •Autoclave method for producing α-hemihydrate
- •Gypsum boiling kettle for the production of ß-hemihydrate
- •5 Level (12 points)
- •The high temperature burning of gypsum method (multiphase gypsum) on the grate
- •Properties capable of hardening calcium sulphates
- •Hydration CaSo4-binding
- •Natural -, uusdg - and chemical anhydrite
- •The properties of the treated gypsum building materials
- •Other areas of application
- •The norms, chemical analysis and phase analysis
- •Gypsum Products
- •The requirements of gost 125-79 for the quality of construction gypsum
- •Other inorganic binding materials
- •Alumina cement
- •Production of alumina cement
- •Chemical and mineralogical composition of the alumina cement
- •Areas of use alumina cement
- •Softeners (plasticizers), added during the production concrete
- •Softeners (plasticizers), added to the concrete mix
- •Concrete
- •Mobile concrete plants
- •Concrete for precast concrete elements
- •Self-compacting concrete
- •Building mortar
- •Cement mortar
- •Plaster
- •Cementing deep wells
Areas of use alumina cement
Aluminous cement strength (GOST 969-77) is divided into grade 400, 500 and 600, determined by the test results in compression size prisms halves 4X4X16 cm, made of low ductility of a 1: 3 (GOST 310.1-76 rev.) And tested through 3 days hardening. After 1 day of hardening cement 80-90% three-day prochnosti.Dlya hardening alumina cement are most favorable water conditions. Both air and combined air-wet storage is accompanied by a significant drop in the strength of concrete in this cement in the late periods of hardening (at 50- 60% in 10-20 years). Durability decreases sometimes willows first month hardening. GOST 969-77 not allowed to decrease the tensile strength of samples 28-sous-exact age strength compared to three-day-aged samples more than 10%. At low temperatures (5-10 ° C), aluminous cement hardens quite rapidly due to significant heat release, as indicated on ranee.Betony alumina cement are characterized by high resistance to water, frost and heat resistance. The water resistance of cement due, in particular, the lack of products of hydration calcium hydroxide, characterized by, as is known, a considerable water solubility (1.2 g / L at ordinary temperature CaO).
Softeners (plasticizers), added during the production concrete
Breakers, sometimes referred to as plasticizers (Engl. "Plasticizer"), reduce the viscosity (in professional language "Concrete Technology" is called "consistency") concrete. Building material becomes thinner and thus easier to handle. One of the other applications is the so-called plasticisers less water (water saving) in concrete or cement and / or gypsum solutions. In this case, by using a plasticizer water / cement ratio, without degrading the consistency can be reduced or the processing capabilities of the construction material.
The most widely used is the lignosulfonate (sometimes referred to as lignin sulfonate, or sulfonated lignin). They are the Na, Ca salts of lignosulfonic acid, is used in liquid, solid or powder form. This thinning effects was discovered in 1920 during the construction of roads in the United States. At the time, it was customary to give a dark colored certain lane carriageway by spraying the waste lye containing lignin. It was found that lignin product will not only change the color of the concrete road, but also thins (plasticized) it. Thus, it was found lignosulfonate plasticizing effect. Today, in the construction industry uses annually about 600 000 tons of lignosulphonate. Thus, this additive count occupies first place among the construction of chemical additives.
Lignosulfonate is made from wood lignin (lat. Lignum = wood). Wood contains an average of from 20 to 30% lignin (mainly cortex), 60-70% golotsellyulozy (hemicellulose and cellulose fibers) and 10% water. Depending on the type of tree having various lignins. There are lignins from soft wood (eg fir and pine trees), solid lignin trees (eg oak, beech and eucalyptus) and lignin from grasses. In each case, a different part of the lignin. Figure 2.1 shows the approximate composition of spruce lignin, which is often used in the form of raw materials [219]. Lignin from herbs in the chemical industry is almost never used. The hydrophobic lignin protects plants from injuries caused by a fungus, microbes and insects. In addition, it gives a certain toughness plant material.
