- •1 Level (6 points)
- •History of the need for building materials
- •Cement production in the Republic of Kazakhstan
- •The history of obtaining and production cement
- •Economics of cement production
- •Determination of clinker, cement and additives introduced in the grinding
- •The composition of the raw meal. Equations 1-4
- •The composition of the raw meal. Equations 5-9
- •An overview of phase composition and quality phase of clinker
- •Portland cement clinker.
- •Chemical and mineralogical composition alite
- •Chemical and mineralogical composition of belite
- •Phase aluminate
- •Phase Ferrite
- •Other clinker phases
- •The composition and place of origin of the phases in portland cement clinker
- •Analysis of the raw meal, cement and clinker
- •Microscopic research of clinker
- •Recent developments in the use of X-rays
- •Petrographic analysis of clinker
- •Cement production
- •Raw materials and fuels in cement production
- •The raw materials of cement industry
- •Limestone and clay
- •A natural mixture of clay and limestone
- •Waste and their use in the cement industry
- •2 Level (6 points)
- •Mining, processing of raw materials, grinding of raw meal and homogenisation.
- •The blending warehouse of raw materials and its functions.
- •Development of the pile by rotary excavator
- •The process of burning cement clinker. General concepts
- •Chemical reactions during heat treatment of portland cement raw meal (main reaction clinker burning)
- •The dehydration of kaolinite
- •The reactions during the sintering
- •Reaction with cooling
- •Homogeneity of the raw meal
- •The process of burning cement clinker
- •Procedures for burning cement clinker
- •Decarbonizators with upward vertical gas flue.
- •The fuel in cement production
- •Clinker cooler
- •Cooler sf (Smidth-Fuller).
- •Storage of clinker
- •Cement Grinding
- •Milling equipment
- •The fineness of grinding and particle size distribution (grain) composition of the cement
- •Storage, packing, shipment cement to the consumer
- •The granulated blast furnace slag (s)
- •Pozzolan (p, q)
- •Natural pozzolanic additives (р)
- •Natural volcanic pozzolanic additives (q)
- •3 Level (8 points)
- •Fly ash rich in silica (V)
- •Lime ash dust (w)
- •Calcined shale (t)
- •Limestone (l, ll)
- •The quartz dust (d)
- •Small components
- •Calcium sulphate
- •The cement admixture
- •Cement according to standard
- •Physical and chemical properties of cements according to European standard
- •Cements with special properties
- •Well cement
- •Hydration
- •The reaction of silicates (c3s, c2s)
- •Hydration c3s
- •Hydration c2s
- •Reactions of hydration aluminate without participation of sulfates
- •Reactions hydration aluminate with participation sulphates
- •Hydration ferrite (c4af)
- •Taylor Model
- •Model Stark
- •The cement hydration
- •Reaction of the secondary components
- •Hydration of cement containing granulated slag
- •Reactions pozzolanic materials
- •4 Level (8 points)
- •Slowing solidification
- •Structure of a cement stone
- •Building lime
- •The historical and economic situation. Raw material deposits
- •Production and processing of limestone
- •Burning lime
- •Shaft kiln to coke (coal) and gas fuel
- •The rotary tube kiln
- •Counter current regenerative kiln (ggr-kiln)
- •Shaft ring kiln
- •Grinding and shipment of burnt lime
- •Slaked lime
- •The use of lime products
- •The requirements of stst 9179-79 to building lime
- •Gypsum. History and economy
- •Physical and chemical bases of gypsum binders
- •Phases in the system CaSo4 - h2o
- •The crystal structures, double salts, mixed crystals
- •Natural gypsum, natural anhydrite
- •The chemical gypsum
- •Uddg- gypsum
- •Production of calcium sulphate binders
- •Technological processes in the production of calcium sulphate binders
- •Autoclave method for producing α-hemihydrate
- •Gypsum boiling kettle for the production of ß-hemihydrate
- •5 Level (12 points)
- •The high temperature burning of gypsum method (multiphase gypsum) on the grate
- •Properties capable of hardening calcium sulphates
- •Hydration CaSo4-binding
- •Natural -, uusdg - and chemical anhydrite
- •The properties of the treated gypsum building materials
- •Other areas of application
- •The norms, chemical analysis and phase analysis
- •Gypsum Products
- •The requirements of gost 125-79 for the quality of construction gypsum
- •Other inorganic binding materials
- •Alumina cement
- •Production of alumina cement
- •Chemical and mineralogical composition of the alumina cement
- •Areas of use alumina cement
- •Softeners (plasticizers), added during the production concrete
- •Softeners (plasticizers), added to the concrete mix
- •Concrete
- •Mobile concrete plants
- •Concrete for precast concrete elements
- •Self-compacting concrete
- •Building mortar
- •Cement mortar
- •Plaster
- •Cementing deep wells
Building lime
In the production of building materials and as raw material for processing of some surfaces is widely used lime. Lime produced by calcination in special furnaces equipped with a temperature of 1000 to 1200 degrees carbonate rocks. Thermally treated lime takes the form of irregularly shaped pieces that are in the process of further use is subject to various processing.
Chemical composition formula and lime
For lime production does not apply any chemical catalysts, the main condition for its receipt, only the respective thermal regime. This is produced in the manufacturing process is completely natural material, it permitted content of impurities of small lime clay.
Limestone, CaCO3 formula has, as is predominantly calcium. In the process of temperature influence the carbon dioxide is released and produced raw materials has the formula CaO.
Razgashennaya lime can be in several states:
• fluff or a fine powder obtained by mixing lime with water, the pieces, and the moisture percentage should be from 60 to 70%.
• lime dough - a starting material compound with water, it takes about 3.5 times greater. As a result of such cancellation, a dense mass that is used in various fields.
• If lumps dissolve lime with water in the ratio of 1:10, it is possible to obtain lime milk. This slaked lime used for whitewashing the interior of buildings, facades, household outbuildings.
• When slaked lime for a long time is not used, the process is reversed, ie, the solution absorbs carbon dioxide and hardens. On sale you can often meet lime - hydrated lime or lumpy.
Technical properties
For the production of quicklime and quicklime special requirements regulated by the state standard (GOST 9179-77):
1) In the production of lime is used only carbonate rocks and some mineral supplements. The amount of additives should not exceed the amount specified in the standards for certain varieties of lime.
2) Quicklime divided into three classes and should not contain additives, powdery additives available in two varieties, slaked may or may not have additives, and is distributed in two classes.
3) calcium lime is calcium the main component, MgO percentage should not exceed 5.
4) Dolomitizirovanayaya lime contains up to 20% MgO
5) Dolomite 40% MgO.
6) In the hydraulic may include silica, iron oxide, a small amount of clay.
lime properties are defined primenyamymi during firing rocks and by the manufacturing process. As a result of the heat treatment furnace limestone out solid pieces quicklime depends on the color additives present, shade whiter than the higher grade material. Dolomitic lime and hydraulic grayish ottenok.Pri have contact with water releases carbon dioxide and lime becomes liquid, the concentration of which depends on the amount of water. Depending on the process and the firing temperature can be obtained by varying the strength of lime - firmly deification, intermediate variant and softly deified.
Stamps and some types of lime
Lime and divided by grades and primary raw materials used.
View and lime and the main brand is defined by its scope:
• Construction of lime produced from calcium and magnesium species. Apply lime building for administration as a plasticizer in the concrete mixtures, solutions. Building lime comes in lumps, in the form melkoypushonki or lime putty.
• Hydraulic lime - calcine limestone containing from 6 to 20% clay impurities. This kind of use of lime for the production of concrete of low marks, as a par with high strength, it has a low ductility. Hydraulic lime is often used in the construction of buildings, operation of which involves finding in a moist environment.
• lump lime is a semi-finished product used for the manufacture of powdered raw materials or solutions. The lumps of lime stored in closed warehouses, protected from humidity. Lump lime is marketed for the preparation of solutions for whitewashing.
• Gardening lime needed for the enrichment of acidic soils. In acidic soils minimum calcium content, which leads to poor growth and development of plants. Introduction of hydrated and quick lime in the soil is carried out in the spring or autumn, and preferably during the rainy season, so the limestone is more soluble. Do not make use of lime along with other fertilizers, and during operation is required to protect the eyes and hands.
• sodium (soda) limestone - porous white mass, which is a mixture of sodium hydroxide and hydrated lime. Soda lime is used as an absorber of carbon dioxide and moisture from the air. It is used in chemical laboratories for the production of gas masks, diving equipment. In medicine, used as a sorbent for anesthesia devices and hyperbaric chambers.
• Bleach is obtained in the course of a complex combination of free chlorine and calcium hydroxide. Bleach has strong disinfectant properties, previously used in its pure form in health care facilities. Today, chlorine is used for disinfection of latrines, cesspools, for the production of solutions for disinfection. Bleach has and bleaching properties.
Production and manufacturing technology
Lime production generally consists of two phases:
1) Quarry limestone and other rocks used. For the production of lime Komkova can use and waste production, using limestone for other purposes.
2) Roasting prepared rocks.
Limestone is mined in open pit quarries using explosives. Selective mining of rocks allows you to prepare the raw material, uniform in its density and chemical composition, which affects the quality of lime produced in the future.
Firing limestone - the main stage of the process of manufacturing an air lime. Depending on the impurities content and use different temperature conditions. All technological conditions must be met, as the limestone burned leads to low quality characteristics of the material. Dead burned lime is poorly soluble in water, has a high density and a negative impact on concrete solutions.
Calcination of the starting material is carried out in different furnaces. Widely used shaft furnaces, they are characterized by a continuous cycle of operation, efficiency, ease of management. Rotary kilns myagkoobozhennuyu allow to obtain the highest quality lime.
Developed and used by installation allows for the firing of the material in a fluidized bed or in suspension. Such systems make good use of the firing of the smallest fractions of rocks, but they have low efficiency.
