- •Introduction
- •Chapter # 1. The foundations of atomic-molecular studies. The laws and concepts of stoichiometry
- •Vocabulary
- •Subject and Tasks of Chemistry
- •General notions of atomic-molecular studies
- •Number of atoms of an element
- •Example of solution
- •Amount of substance. Mole. Avogadro’s Number. Molar mass
- •Number of moles of an element
- •Mass of an element (grams)
- •X Molar mass of element (Mm)
- •4. The laws and concepts of Stoichiometry
- •5. Types of chemical reactions
- •Chapter # 2. Atomic structure
- •Vocabulary
- •General notions
- •Theories of atomic structure
- •Figure 3. Spatial orientation of p-orbitals
- •3. Principles for distribution of electrons in atoms Distributions of electrons in atoms on energy levels and sub-levels may be presented in the form of electronic formulas.
- •Ground state
- •4. Valency and Oxidation number as function of electrons distribution
- •Practice problems
- •Chapter # 3. The periodic law and periodic table of chemical elements
- •Vocabulary
- •1. Formulation
- •2. Physical meaning of the chemical periodicity
- •3. The Periodic Table
- •Periodical table of chemical elements named by d.I. Mendeleev
- •Practice problems
- •Chapter # 4. Chemical bonding
- •Vocabulary
- •Types of Chemical Bonds
- •Ionic bond
- •Nonpolar-covalent bond
- •P olar-covalent bond
- •Figure 10. Formation of Hydrogen Bonds between water molecules
- •Figure 11. Depending of boiling-points (b.Pt) of double Hydrogen-contained compounds from nature of the second atom and presence of Hydrogen bonding
- •Why does Chemical Bond occur?
- •Practice problems
- •Сhapter # 5. Laboratory glassware, labware and rules of laboratory research
- •Vocabulary
- •Chemical glassware
- •2. Chemical reagents and their storage
- •3. Elementary operations carrying out
- •4. Safety rules during carrying out laboratory works
- •5. Rules for reagents and equipment use
- •6. Rules for work carrying out and results design
- •Chapter # 6. The main classes of inorganic compounds
- •Vocabulary
- •Classification of inorganic substances
- •Inorganic substances
- •Compounds
- •2. Relation between main classes of inorganic substances
- •3. Oxides
- •Preparation
- •Chemical properties
- •4. Bases
- •Preparation
- •Chemical properties
- •5. Acids
- •Preparation
- •Chemical properties
- •6. Amphoteric hydroxides
- •Preparation
- •7. Salts
- •Preparation
- •Chemical properties
- •Chemical properties
- •6. Thermal decomposition with medium salts formation:
- •Structural-graphic formulas of chemical compounds
- •Example of solution
- •Chapter # 7. Theory of electrolytic dissociation
- •Vocabulary
- •Solutions
- •Concentration of solutions
- •Molarity (molar concentration)
- •Theory of dissociation
- •Degree of dissociation
- •Main classes of inorganic substances from viewpoint of theory of electrolytic dissociation
- •6. Ionic equations
- •Laboratory training
- •Chapter # 8. Ionic product of water. Hydrolysis of salts
- •Vocabulary
- •Ionic product of water. Notion of pH
- •General notion of Hydrolysis
- •Different types of Hydrolysis
- •Laboratory training Experiment 1. Identification of reaction medium in solutions of salts
- •Experiment 2. Influence of temperature to hydrolysis
- •Chapter # 9. Oxidation-reduction reactions
- •Vocabulary
- •1. Oxidation of Elements
- •2. Oxidation-Reduction Reactions
- •3. Compiling Equations of Oxidation-Reduction Reactions
- •4. Most Important Oxidizing and Reducing Agents
- •Types of Redox Reactions
- •Influence of Medium to Redox Reactions
- •Electromotive Series of Metals
- •Vocabulary
- •1. General characteristics
- •Laboratory training Experiment 1. Reducing properties of metal ions of lower oxidation number
- •Chapter # 10. Complex (coordination) compounds
- •2. Nomenclature
- •3. Rules for naming of coordination compounds
- •Laboratory training
- •Chapter # 11. The halogens
- •Vocabulary
- •1. General characteristics
- •2. Chlorine
- •Laboratory training
- •Experiment 2. Halogens oxidative activity in free state
- •Experiment 5. The salts of hydrohalogen acids insoluble in water
- •Chapter # 12. The chalcogens
- •Vocabulary
- •1. General characteristics
- •Industrial Information
- •2. Oxygen
- •3. Sulfur
- •Experiment 6. Dilution of concentrated Sulfuric acid
- •Experiment 9. Instability of thiosulfuric acid
- •Chapter # 13. Nitrogen, phosphorus
- •Vocabulary
- •1. General characteristics
- •Industrial Information
- •2. Nitrogen
- •3. Phosphorus
- •Phosphorus behaves as the typical non-metal. It reacts with Oxygen, formed acid oxides:
- •Experiment 2. Oxidation and reducing power of nitrous acid and Nitrites
- •Chapter # 14. Chemistry of main biometals
- •Vocabulary
- •1. The Alkali Metals
- •Industrial Information
- •2. Other bioactive metals
5. Types of chemical reactions
Chemical reactions are processes by which atoms or molecules are redistributed, resulting in different substances with unique properties. Chemical reactions are classified into different categories according to the mechanics of the reactions. The original elements or compounds involved in a chemical reaction are called reactants, and the chemicals that result are called products. Classification of types is presented in Table 2.
Table 2. Types of chemical reactions
-
Type
Scheme
Example
Synthesis (combination, construction, composition) reactions
X + Y = Z, where
X, Y are elements or compounds;
Z - new compound
2 H2 + O2 = 2H2O;
H2O + SO3 = H2SO4;
K2O + CO2 = K2CO3
Decomposition (desythesis, decomposition, deconstruction) reactions
XZ = X + Z
2 KClO3
3 O2↑
+ 2 KCl ;6NaHCO3 3 Na2CO3 + 3 CO2↑ + 3H2O;
2 AgI 2 Ag + I2
Single replacement (single displacement, single substitution, activity replacement) reactions
A + BX = B + AX
2 Mg + TiCl4 Ti + 2 MgCl2;
2 Al + 6 CaO Ca3(AlO3)2 + 3 Ca;
Double replacement (double displacement or metathesis) reactions
AB + CD = AD + CB
AgNO3 + KCl = AgCl↓ + KNO3;
TiCl4 + H2O = 4 HCl↑ + TiO2↓;
HCl + NaOH = NaCl + H2O
Oxidation-reduction reactions (Red-Ox)
Az + n
→
A (z
- n)By - m → B (y+m)
2Na + S → Na2S;
2 KMnO4 K2MnO4 + MnO2 + O2
Acid-Base reactions (neutralization)
H+ + OH- → H2O (in net ionic form)
H2SO4 + 2 NaOH = Na2SO4 + 2H2O
PRACTICE PROBLEMS
1. To determine relative molecular mass and molar mass of Potassium Orthophosphate К3РО4.
2. How many atoms and moles of atoms are contained in 64 g of Oxygen 16О? To calculate a mass of one atom of Oxygen in grams.
3. How many moles of H2SO4 are contained in 4,9 grams of this substance?
4. How many moles of Sulfuric acid is it possible to prepare from 6,4 kg of Sulfur?
5. How many moles of slack lime Са(ОН)2 is it possible to prepare from 0,1 g of chalk СаСО3 if chalk completely changed into slack lime?
6. To calculate mass (in g) of molecules of Chlorine Cl2, Carbonic gas CO2, ammonia gas NH3.
7. How many grams of Barium Sulfate BaSO4 may be prepared from 6,1 g of salt BaCl22H2O? To calculate the mass of Sulfuric acid used in this reaction.
8. Solution, contained 12,6 g of Nitric acid HNO3, was mixed with 7,2 g of Caustic soda NaOH. What substance will be rest in surplus and in which quantity?
